[1,2-双（吡啶-2-基甲氧基）苯-κN,O,O',N']双（硝酸根-κO）钴（II）
[1,2-Bis(pyridin-2-ylmeth-oxy)benzene-κN,O,O',N']bis-(nitrato-κO)cobalt(II).
作者信息
Huang Nan-Nan, Yu Ying-Hui, Liu Ying, Hou Guang-Feng, Gao Jin-Sheng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m598. doi: 10.1107/S1600536811013328. Epub 2011 Apr 16.
Abstract
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))], the Co(II) ion is six-coordinated in a distorted octa-hedral environment defined by two O and two N atoms from the ligand and by two O atoms from two nitrate anions. A two-dimensional network parallel to the ab plane is built up by C-H⋯O hydrogen bonds, which link adjacent mol-ecules in the crystal structure.
摘要
在标题化合物[Co(NO₃)₂(C₁₈H₁₆N₂O₂)]中，Co(II)离子在一个扭曲的八面体环境中进行六配位，该环境由来自配体的两个O原子和两个N原子以及来自两个硝酸根阴离子的两个O原子界定。通过C—H⋯O氢键构建了一个平行于ab平面的二维网络，这些氢键将晶体结构中的相邻分子连接起来。
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