Wöhlert Susanne, Jess Inke, Näther Christian
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m693-4. doi: 10.1107/S1600536811016199. Epub 2011 May 7.
The crystal structure of the title compound, {[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n), consists of two crystallographically independent Mn cations, four seleno-cyanate anions, four 1,2-di-pyridylethylene (bpe) ligands (two of which are located on centers of inversion) and two bpe solvent molecules. Each manganese(II) cation is coordinated by two terminally N-bonded seleno-cyanate anions and four bpe ligands within a slightly distorted octa-hedron. The manganese(II) cations are linked by the bpe ligands into chains that are further connected by these ligands into layers. These layers are stacked, forming cavities in which additional bpe solvent molecules are embedded.
标题化合物{[Mn(NCSe)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2)}(2n)的晶体结构由两个晶体学独立的锰阳离子、四个硒氰酸根阴离子、四个1,2 - 二吡啶基乙烯（bpe）配体（其中两个位于对称中心）和两个bpe溶剂分子组成。每个锰（II）阳离子在一个轻微扭曲的八面体中由两个末端N键合的硒氰酸根阴离子和四个bpe配体配位。锰（II）阳离子通过bpe配体连接成链，这些链再通过这些配体进一步连接成层。这些层相互堆叠，形成了嵌入额外bpe溶剂分子的空腔。
