Wöhlert Susanne, Wriedt Mario, Jess Inke, Näther Christian
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m965. doi: 10.1107/S1600536812027742. Epub 2012 Jun 23.
Reaction of cobalt(II) nitrate with potassium seleno-cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio-cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno-cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.
硝酸钴(II)与硒氰酸钾和哒嗪反应生成标题化合物[Co(NCSe)₂(C₄H₄N₂)₄]·2C₄H₄N₂的单晶,该化合物与其硫氰酸镍(II)类似物同型。Co²⁺阳离子由两个通过N键合的硒氰酸根配体和来自四个哒嗪配体的四个N原子配位形成离散的配合物。这些配合物排列成平行于(001)的层。这些层被额外的非配位哒嗪配体隔开。