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链状聚[[[双(3-羟基金刚烷-1-羧酸根-κO)(3-羟基金刚烷-1-羧酸-κO)锌(II)]-μ(2)-4,4'-联吡啶]一水合物]

catena-Poly[[[bis-(3-hy-droxy-adamantane-1-carboxyl-ato-κO)(3-hy-droxy-adamantane-1-carb-oxy-lic acid-κO)zinc(II)]-μ(2)-4,4'-bipyridine] monohydrate].

作者信息

Shen Jin-Bei, Guan Quan-Yin, Chen Xiao-Ju, Zhao Guo-Liang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m715-6. doi: 10.1107/S1600536811016424. Epub 2011 May 7.

Abstract

In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Formula: see text]01]. O-H⋯O hydrogen bonds help to consolidate the packing.

摘要

在标题配位聚合物{[Zn(C₁₁H₁₅O₃)₂(C₁₀H₈N₂)(C₁₁H₁₆O₃)]·H₂O}ₙ中,Zn(II)离子由两个4,4'-联吡啶(4,4'-bpy)分子中的两个N原子以及两个3-羟基金刚烷-1-羧酸根阴离子(L)和一个3-羟基金刚烷-1-羧酸(HL)分子中的三个O原子进行五配位。所得的配位多面体是一个近乎规则的ZnN₂O₃三角双锥,N原子位于轴向位置。4,4'-bpy分子[芳环之间的二面角 = 17.2 (2)°]充当桥连基团,将金属离子连接成在[[化学式:见原文]01]方向延伸的无限聚合物链。O—H⋯O氢键有助于巩固堆积结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f2/3120402/68187c725fef/e-67-0m715-fig1.jpg

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