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链状聚[[[水合-(5-羧基吡啶-3-羧酸根合-κN)铜(I)]-μ-4,4'-联吡啶-κN:N']一水合物]

catena-Poly[[[aqua-(5-carb-oxy-pyridine-3-carboxyl-ato-κN)copper(I)]-μ-4,4'-bipyridine-κN:N'] monohydrate].

作者信息

Liu Gang, Qin Gao

机构信息

College of Food Engineering, Jilin Teachers' Institute of Engineering and Technology, 130052 Changchun, Jilin, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m120. doi: 10.1107/S1600536811055656. Epub 2012 Jan 7.

Abstract

In the title compound, {[Cu(C(7)H(4)NO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cu(I) ion is coordinated by the N atom from a 5-carb-oxy-pyridine-3-carboxyl-ate anion, two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands and one water mol-ecule in a distorted tetra-hedral geometry. The 4,4'-bipy ligands bridge the Cu(I) ions into polymeric chains propagating in [201]. The latticeand the coordinating water mol-ecules as well as the carboxy OH function are involved in the formation of inter-molecular O-H⋯O hydrogen bonds, which consolidate the crystal packing.

摘要

在标题化合物{[Cu(C₇H₄NO₄)(C₁₀H₈N₂)(H₂O)]·H₂O}ₙ中,Cu(I)离子由一个5-羧基吡啶-3-羧酸根阴离子的N原子、两个4,4'-联吡啶(4,4'-bipy)配体的两个N原子和一个水分子配位,形成扭曲的四面体几何构型。4,4'-bipy配体将Cu(I)离子桥连形成沿[201]方向延伸的聚合物链。晶格以及配位水分子和羧基OH官能团参与分子间O-H⋯O氢键的形成,从而巩固了晶体堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2495/3274861/89ca2f00a456/e-68-0m120-fig1.jpg

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