反式双（3-羟基吡啶-κN）二碘铂（II）二甲亚砜溶剂合物
trans-Bis(3-hy-droxy-pyridine-κN)diiodidoplatinum(II) dimethyl sulfoxide disolvate.
作者信息
Huq Fazlul, Danish Muhammed, Starosta Wojciech, Leciejewicz Janusz
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m721. doi: 10.1107/S1600536811015893. Epub 2011 May 7.
Abstract
In the title compound, [PtI(2)(C(5)H(5)NO)(2)]·2(CH(3))(2)SO, the Pt(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment by two trans iodide ligands and two pyridine N atoms. In the crystal, complex mol-ecules and solvent dimethyl sulfoxide mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds.
摘要
在标题化合物[PtI₂(C₅H₅NO)₂]·2(CH₃)₂SO中，Pt(II)离子位于一个对称中心上，在略微扭曲的平面正方形环境中由两个反式碘配体和两个吡啶N原子配位。在晶体中，配合物分子和溶剂二甲基亚砜分子通过分子间O—H⋯O氢键相连。
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