3,3'-二甲基-1,1'-(丙烷-1,3-二亚基)二咪唑-1-鎓双-(1,2-二氰基-乙烯-1,2-二硫醇根合-κS,S')镍(II)
3,3'-Dimethyl-1,1'-(propane-1,3-di-yl)diimidazol-1-ium bis-(1,2-dicyano-ethene-1,2-dithiol-ato-κS,S')nickelate(II).
作者信息
Yu Shan-Shan, Duan Hai-Bao, Ren Xiao-Ming
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1117. doi: 10.1107/S1600536811027693. Epub 2011 Jul 23.
Abstract
In the title compound, (C(11)H(18)N(4))[Ni(C(4)N(2)S(2))(2)], the asymmetric contains one half-complex, with the cation placed on a twofold axis and the anion located on an inversion center. The Ni(II) ion in the anion is coordinated by four S atoms of two maleonitrile-dithiol-ate ligands, and exhibits the expected square-planar coordination geometry.
摘要
在标题化合物（C₁₁H₁₈N₄）[Ni（C₄N₂S₂）₂]中，不对称单元包含一个半配合物，阳离子位于二重轴上，阴离子位于对称中心。阴离子中的Ni（II）离子由两个马来二腈二硫醇盐配体的四个S原子配位，并呈现出预期的平面正方形配位几何构型。
Zotero 插件