Gao Zhu-Qing, Lv Dong-Yu, Gu Jin-Zhong, Li Hong-Jin
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m740. doi: 10.1107/S1600536811016953. Epub 2011 May 11.
In the title coordination polymer, {[Ho(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Ho(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl-ate trianion, two monodentate anions and three water mol-ecules, forming a distorted bicapped trigonal-prismatic HoNO(7) coordination geometry. The anions bridge adjacent Ho(III) ions into double chains. Adjacent chains are further connected into sheets. O-H⋯O hydrogen bonds involving both coordinated and uncoordinated water mol-ecules generate a three-dimensional supra-molecular framework.
在标题配位聚合物{[Ho(C₇H₂NO₅)(H₂O)₃]·H₂O}ₙ中,Ho(III)原子由一个三齿的4-氧化吡啶-2,6-二羧酸根三阴离子、两个单齿阴离子和三个水分子八配位,形成扭曲的双帽三角棱柱形HoNO₇配位几何构型。阴离子将相邻的Ho(III)离子桥连形成双链。相邻的链进一步连接成层。涉及配位和未配位水分子的O-H⋯O氢键形成三维超分子框架。