Courtney Donagh, Manning Anthony R, McAdam C John, Simpson Jim
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m742-3. doi: 10.1107/S1600536811016928. Epub 2011 May 14.
In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-penta-dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C-H⋯π inter-actions which generate a three-dimensional network.
在标题化合物[Co(C₁₃H₉)(C₂₈H₂₀)]中,Co原子夹在二面角为2.6(3)°的环戊二烯基环和环丁二烯基环之间。四个苯环相对于环丁二烯基平面倾斜,使得C₄Ph₄单元构成一个四叶螺旋桨。苯乙炔取代基的苯环与环戊二烯基环的夹角为34.92(18)°。晶体结构仅通过C—H⋯π相互作用得以稳定,这些相互作用形成了一个三维网络。