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[η-(苯基-乙炔基)环戊二烯基](η-四苯基环丁二烯)钴(I)

[η-(Phenyl-ethyn-yl)cyclo-penta-dien-yl](η-tetra-phenyl-cyclo-butadiene)cobalt(I).

作者信息

Courtney Donagh, Manning Anthony R, McAdam C John, Simpson Jim

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m742-3. doi: 10.1107/S1600536811016928. Epub 2011 May 14.

Abstract

In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-penta-dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C-H⋯π inter-actions which generate a three-dimensional network.

摘要

在标题化合物[Co(C₁₃H₉)(C₂₈H₂₀)]中,Co原子夹在二面角为2.6(3)°的环戊二烯基环和环丁二烯基环之间。四个苯环相对于环丁二烯基平面倾斜,使得C₄Ph₄单元构成一个四叶螺旋桨。苯乙炔取代基的苯环与环戊二烯基环的夹角为34.92(18)°。晶体结构仅通过C—H⋯π相互作用得以稳定,这些相互作用形成了一个三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3120504/a537c30ed4fb/e-67-0m742-fig1.jpg

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