[η-1,3-双（三甲基硅基）环戊二烯基]二氯[η-（三甲基硅基）环戊二烯基]钛（IV）
[η-1,3-Bis(trimethyl-sil-yl)cyclo-penta-dien-yl]dichlorido[η-(trimethyl-sil-yl)cyclo-penta-dien-yl]titanium(IV).
作者信息
Perdih Franc
机构信息
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, PO Box 537, SI-1000 Ljubljana, Slovenia, and CO EN-FIST, Dunajska 156, SI-1000 Ljubljana, Slovenia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1693. doi: 10.1107/S1600536811046228. Epub 2011 Nov 5.
In the title compound, [Ti(C(8)H(13)Si)(C(11)H(21)Si(2))Cl(2)], the Ti(IV) atom is bonded to two Cl atoms, one 1,3-bis-(trimethyl-sil-yl)cyclo-penta-dienyl (Si(2)Cp) and one (trimethyl-sil-yl)cyclo-penta-dienyl ring (SiCp). The Si(2)Cp centroid-titanium distance is 2.0763 (10) Å and the SiCp centroid-titanium distance is 2.0793 (10) Å. The angle subtended at the Ti atom by the centroids of both cyclo-penta-dienyl rings is 131.22 (4)° and the Cl-Ti-Cl angle is 94.14 (2)°.
在标题化合物[Ti(C₈H₁₃Si)(C₁₁H₂₁Si₂)Cl₂]中，Ti(IV)原子与两个Cl原子、一个1,3-双（三甲基硅基）环戊二烯基（Si₂Cp）和一个（三甲基硅基）环戊二烯基环（SiCp）相连。Si₂Cp质心与钛的距离为2.0763(10) Å，SiCp质心与钛的距离为2.0793(10) Å。两个环戊二烯基环的质心在Ti原子处形成的夹角为131.22(4)°，Cl-Ti-Cl角为94.14(2)°。
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