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聚[μ(3)-氯-μ(2)-氯二氯(μ-二甲基亚砜-κO:S)(二甲基亚砜-κO)(μ-嘧啶-κN:N')-钌(III)钠]

Poly[μ(3)-chlorido-μ(2)-chloridodichlorido(μ-dimethyl sulfoxide-κO:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κN:N')-ruthenium(III)sodium].

作者信息

Ferrara Skylar, Kreider-Mueller Ava, Tanski Joseph M, Anderson Craig M

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m756-7. doi: 10.1107/S1600536811017211. Epub 2011 May 14.

DOI:10.1107/S1600536811017211
PMID:21754645
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120471/
Abstract

The title complex, NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2), is the sodium salt of monoanionic octa-hedral Ru(III)Cl(4)(pyrimidine)(DMSO) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (11) Å, respectively. The complex forms a chain, with a six-coordinate sodium ion bridging the ruthenium(III) units. The sodium cation is coordinated by cis-chloride ligands on ruthenium [Na-Cl = 2.9576 (7) and 2.6988 (7) Å], chloride and DMSO ligands from the ruthenium complexes related by inversion [Na-Cl and Na-O = 2.8888 (7) and 2.2623 (12) Å, respectively], a nitro-gen ligand from the pyrimidine of the tetrachlorido-ruthenium(III) complex related by the twofold rotation axis [Na-N = 2.5224 (14) Å] and an oxygen-bound DMSO [Na-O = 2.3165 (12) Å].

摘要

标题配合物[NaRuCl₄(C₄H₄N₂)(C₂H₆OS)₂]ₙ是单阴离子八面体[Ru(III)Cl₄(嘧啶)(DMSO)]⁻的钠盐，其中硫键合的二甲基亚砜（DMSO）和嘧啶配体在Ru(III)原子上彼此呈反式取向。四个Ru-Cl键长的平均值为2.355 (15) Å，Ru-S和Ru-N键长分别为2.2853 (3) Å和2.1165 (11) Å。该配合物形成一条链，六配位的钠离子桥连钌(III)单元。钠离子由钌上的顺式氯化物配体配位[Na-Cl = 2.9576 (7) 和2.6988 (7) Å]、来自通过反演相关的钌配合物的氯化物和DMSO配体[Na-Cl和Na-O分别为2.8888 (7) 和2.2623 (12) Å]、来自通过二重旋转轴相关的四氯钌(III)配合物嘧啶的氮配体[Na-N = 2.5224 (14) Å]以及氧键合的DMSO[Na-O = 2.3165 (12) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bde/3120471/6fd65b9fc932/e-67-0m756-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bde/3120471/689502285be6/e-67-0m756-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bde/3120471/6fd65b9fc932/e-67-0m756-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bde/3120471/689502285be6/e-67-0m756-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bde/3120471/6fd65b9fc932/e-67-0m756-fig2.jpg

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本文引用的文献

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Ruthenium complexes as anticancer agents.钌配合物作为抗癌剂。
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