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N-苄基-6-脱氧-3,6-亚氨基-亚甲基-1,2,3,5-O-四乙酰基-α-D-1(S)-表阿洛呋喃糖

N-Benzyl-6-de-oxy-3,6-imino-methyl-ene-1,2,3,5-O-tetra-acetyl-α-d-1(S)-epiallo-furan-ose.

作者信息

Zhang Qiurong, Wu Chunli, Li Pengyun, Cheng Weiyan, Liu Hongmin

机构信息

New Drug Reseach & Development Center, Zhengzhou Univresity, Zhengzhou 450001, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1545. doi: 10.1107/S1600536811019702. Epub 2011 May 28.

Abstract

The mol-ecule of the title compound, C(22)H(27)NO(9), an azasugar derivative, consists of one benzene ring and two fused rings, which have the cis arrangement at the ring junctions, and gives a V-shaped geometry. The inter-planar angle between the five- and six-membered rings is 65.69 (11)°. The crystal structure is stablized by weak inter-molecular C-H⋯O hydrogen bonds.

摘要

标题化合物C(22)H(27)NO(9)(一种氮杂糖衍生物)的分子由一个苯环和两个稠环组成,它们在环连接处呈顺式排列,呈V形几何构型。五元环和六元环之间的面间角为65.69 (11)°。晶体结构通过弱分子间C-H⋯O氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/391f/3120565/6e272dad3cf1/e-67-o1545-fig1.jpg

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