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3,6-二脱氢-5-羟基-1,2-O-异丙叉基-5-C-硝基甲基-α-D-葡萄糖呋喃糖

3,6-Didehydro-5-hy-droxy-1,2-O-iso-propyl-idene-5-C-nitro-meth-yl-α-d-gluco-furan-ose.

作者信息

Zhang Qiurong, Li Pan, Chen Xuebin, Wang Xiandong, Liu Hongmin

机构信息

New Drug Reseach & Development Center, Zhengzhou Univresity, Zhengzhou 450001, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1673. doi: 10.1107/S160053681102191X. Epub 2011 Jun 18.

Abstract

The title compound, C(10)H(15)NO(7), consists of one methyl-enedi-oxy ring and two fused tetra-hydro-furan rings. The three fused rings exhibit cis arrangements at the ring junctions. One O atom of a tetra-hydro-furan ring and the H atoms bound to the neighboring C atoms are disordered over two orientations with site-occupancy factors of 0.69 (1) and 0.31 (1). intra-molecular O-H⋯O and C-H⋯O inter-actions stabilize the mol-ecular conformation. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O inter-actions link the mol-ecules into a three-dimensional network.

摘要

标题化合物C(10)H(15)NO(7)由一个亚甲基二氧环和两个稠合的四氢呋喃环组成。这三个稠合环在环连接处呈现顺式排列。一个四氢呋喃环的一个O原子以及与相邻C原子相连的H原子在两个取向上无序排列,占位因子分别为0.69 (1)和0.31 (1)。分子内的O—H⋯O和C—H⋯O相互作用稳定了分子构象。在晶体结构中,分子间的O—H⋯O和C—H⋯O相互作用将分子连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cef8/3151982/af002493500f/e-67-o1673-fig1.jpg

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