通过反 Buchner 反应从环庚三烯中生成金(I)卡宾的环丙烷化反应。
Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes.
机构信息
Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
出版信息
J Am Chem Soc. 2011 Aug 10;133(31):11952-5. doi: 10.1021/ja205046h. Epub 2011 Jul 20.
PMID:21761870
Abstract
Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.
摘要
阳离子金（I）促进了 7-取代的 1,3,5-环庚三烯的反 Buchner 反应，生成了可以环丙烷化烯烃的金（I）卡宾。
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