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一维配位聚合物通过单晶到单晶转变的变色和光二聚行为。

Solvochromic and photodimerization behaviour of 1D coordination polymer via single-crystal-to-single-crystal transformation.

机构信息

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

出版信息

Chem Commun (Camb). 2011 Sep 7;47(33):9384-6. doi: 10.1039/c1cc13018h. Epub 2011 Jul 18.

DOI:10.1039/c1cc13018h
PMID:21769348
Abstract

The coordination polymer [Zn(2)(1,2-bda)(2)(bpe)]·MeOH, which exhibits solvochromic effects upon reversible linear alcohol removal and adsorption, can be turned into [Zn(2)(1,2-bda)(2)(tpcb)(0.5)] in two-step SCSC transformations.

摘要

配位聚合物 [Zn(2)(1,2-bda)(2)(bpe)]·MeOH，在可逆线性醇去除和吸附时表现出溶剂致变色效应，通过两步 SCSC 转化可以转化为 [Zn(2)(1,2-bda)(2)(tpcb)(0.5)]。

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