Australian Centre for Microscopy & Microanalysis, University of Sydney, Sydney, New South Wales, Australia.
Phys Rev Lett. 2011 Jun 17;106(24):247002. doi: 10.1103/PhysRevLett.106.247002. Epub 2011 Jun 15.
Local fluctuations in the distribution of dopant atoms are thought to cause the nanoscale electronic disorder or phase separation in pnictide superconductors. Atom probe tomography has enabled the first direct observations of dopant species clustering in a K-doped 122-phase pnictide. First-principles calculations suggest the coexistence of static magnetism and superconductivity on a lattice parameter length scale over a wide range of dopant concentrations. Our results provide evidence for a mixed scenario of phase coexistence and phase separation, depending on local dopant atom distributions.
人们认为,掺杂原子分布的局部波动会导致磷化物超导体中的纳米级电子无序或相分离。原子探针层析成像技术使人们首次能够直接观察到 K 掺杂的 122 相磷化物中掺杂物种的聚类。第一性原理计算表明,在广泛的掺杂浓度范围内,晶格参数长度尺度上的静态磁性和超导性共存。我们的结果为相共存和相分离的混合情景提供了证据,具体取决于局部掺杂原子的分布。