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WO3-富勒烯/TiO2 催化剂的可见光下制备、表征及光催化性能。

Preparation, characterization and photocatalytic behavior of WO3-fullerene/TiO2 catalysts under visible light.

机构信息

Department of Advanced Materials Science & Engineering, Hanseo University, Seosan, Chungnam, 356-706, South Korea.

出版信息

Nanoscale Res Lett. 2011 Jul 20;6(1):459. doi: 10.1186/1556-276X-6-459.

DOI:10.1186/1556-276X-6-459
PMID:21774800
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3211879/
Abstract

WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution under visible light irradiation was used to determine the photocatalytic activity. Excellent photocatalytic degradation of a MO solution was observed using the WO3-fullerene, fullerene-TiO2, and WO3-fullerene/TiO2 composites under visible light. An increase in photocatalytic activity was observed, and WO3-fullerene/TiO2 has the best photocatalytic activity; it may attribute to the increase of the photo-absorption effect by the fullerene and the cooperative effect of the WO3.

摘要

WO3 处理的富勒烯/TiO2 复合材料(WO3-富勒烯/TiO2)通过溶胶-凝胶法制备。通过 BET 表面积测量、X 射线衍射、扫描电子显微镜、能量色散 X 射线分析、透射电子显微镜和 UV-vis 分析对所得到的复合材料进行了表征。使用可见光照射下的甲基橙(MO)溶液来确定光催化活性。WO3-富勒烯、富勒烯-TiO2 和 WO3-富勒烯/TiO2 复合材料在可见光下对 MO 溶液表现出优异的光催化降解性能。观察到光催化活性增加,WO3-富勒烯/TiO2 具有最佳的光催化活性;这可能归因于富勒烯增加了光吸收效果以及 WO3 的协同效应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/fe259c9c2028/1556-276X-6-459-8.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/63c2a4a3d13c/1556-276X-6-459-7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/fe259c9c2028/1556-276X-6-459-8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/bc1237a2f417/1556-276X-6-459-1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/99f1b9d6f4df/1556-276X-6-459-6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/63c2a4a3d13c/1556-276X-6-459-7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ed5/3211879/fe259c9c2028/1556-276X-6-459-8.jpg

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