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掺钛(IV)的 WO₃纳米立方体制备及其可见光驱动光催化性能增强。

Ti(iv) doped WO₃ nanocuboids: fabrication and enhanced visible-light-driven photocatalytic performance.

机构信息

College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Laboratory of Molecular-Based Materials, Anhui Normal University, Wuhu 241000, P. R. China.

出版信息

Nanoscale. 2011 Sep 1;3(9):3695-9. doi: 10.1039/c1nr10460h. Epub 2011 Jul 25.

Abstract

In this paper, we successfully fabricate Ti(iv) doped WO₃ nanocuboids with controlled Ti(iv) contents through a facile, mild, aqueous-phase route. The characterizations clearly exhibit the optimum amount of the Ti(iv) dopant in under these conditions. The obtained photocatalyst shows excellent visible-light-driven photocatalytic performance. It can decompose an organic dye within 70 min under visible-light irradiation. Such a large activity enhancement probably arises from the change of band structure. The results provide an efficient route for the design of photocatalysts with improved visible-light-driven photocatalytic activity as well as a promising material for use in solar cells, nanodevices, and other applications.

摘要

本文通过一种简便、温和的水相法成功制备了具有可控 Ti(iv)含量的 Ti(iv)掺杂 WO₃纳米立方块。这些条件下的最佳 Ti(iv)掺杂量的特性分析清晰地显示了出来。所得到的光催化剂在可见光照射下具有优异的可见光驱动光催化性能。它可以在 70 分钟内分解有机染料。如此大的活性增强可能源于能带结构的变化。研究结果为设计具有改善的可见光驱动光催化活性的光催化剂提供了一条有效途径,同时也为太阳能电池、纳米器件和其他应用提供了一种很有前途的材料。

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