单胺氧化酶 B 催化苄胺和（1,1-(2)H2)苄胺氧化的氮动力学同位素效应：氮重键合和 CH 键断裂不是协同的。
Nitrogen kinetic isotope effects for the monoamine oxidase B-catalyzed oxidation of benzylamine and (1,1-(2)H2)benzylamine: nitrogen rehybridization and CH bond cleavage are not concerted.
机构信息
Department of Biochemistry and Organic Chemistry, Uppsala University, P.O. Box 576, SE-75123 Uppsala, Sweden.
出版信息
J Am Chem Soc. 2011 Aug 17;133(32):12319-21. doi: 10.1021/ja205629b. Epub 2011 Jul 28.
PMID:21786798
Abstract
Nitrogen kinetic isotope effects for the oxidation of benzylamine and (1,1-(2)H(2))benzylamine by recombinant human monoamine oxidase B show that cleavage of the CH bond is not concerted with rehybridization of the nitrogen atom.
摘要
氮动力学同位素效应对重组人单胺氧化酶 B 氧化苄胺和(1,1-(2)H(2))苄胺的影响表明，CH 键的断裂与氮原子的重新杂化不是协同进行的。
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