Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA.
Inorg Chem. 2011 Sep 5;50(17):7925-7. doi: 10.1021/ic2009573. Epub 2011 Jul 27.
Models for the oxidized form of the FeFe hydrogenase active site have been prepared. These cationic complexes contain two iron atoms, carbonyl ligands, a propanedithiolate bridge, and one other bridging group. Reduction of these complexes with hydrogen gas is demonstrated.
已制备出氧化形式的 FeFe 氢化酶活性位点模型。这些阳离子配合物含有两个铁原子、羰基配体、丙二硫醇桥和一个其他桥联基团。这些配合物通过氢气还原得到了证明。
