在温和条件下，通过功能化末端炔烃与芳基硼酸的 Au(I)/Au(III)-催化 Sonogashira 型反应。
Au(I)/Au(III)-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions.
机构信息
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai 200062 (P. R. China).
出版信息
Beilstein J Org Chem. 2011;7:808-12. doi: 10.3762/bjoc.7.92. Epub 2011 Jun 15.
Abstract
A straightforward, efficient, and reliable redox catalyst system for the Au(I)/Au(III)-catalyzed Sonogashira cross-coupling reaction of functionalized terminal alkynes with arylboronic acids under mild conditions has been developed.
摘要
发展了一种用于温和条件下功能化末端炔烃与芳基硼酸的 Au(I)/Au(III)-催化 Sonogashira 交叉偶联反应的直接、高效、可靠的氧化还原催化剂体系。
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