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利用生物模板制备亚波长抗反射纳米结构。

The fabrication of subwavelength anti-reflective nanostructures using a bio-template.

作者信息

Xie Guoyong, Zhang Guoming, Lin Feng, Zhang Jin, Liu Zhongfan, Mu Shichen

机构信息

Centre for Nanoscale Science and Technology (CNST), Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China.

出版信息

Nanotechnology. 2008 Mar 5;19(9):095605. doi: 10.1088/0957-4484/19/9/095605. Epub 2008 Feb 12.

Abstract

This paper describes a paradigm, a simple, low-cost and conventional approach to the fabrication of large-area subwavelength anti-reflective nanostructures on films directly with a bio-template. Specifically, the nano-nipple arrays on the surface of cicada wings have been precisely replicated to a PMMA (polymethyl methacrylate) film with high reproducibility by a technique of replica molding, which mainly involves two processes: one is that a negative Au mold is prepared directly from the bio-template of the cicada wing by thermal deposition; the other is that the Au mold is used to obtain the replica of the nanostructures on the original cicada wing by casting polymer. The reflectance spectra measurement shows that the replicated PMMA film can considerably reduce reflectivity at its surface over a large wavelength range from 250 to 800 nm, indicating that the anti-reflective property has also been inherited by the PMMA film.

摘要

本文描述了一种范例,即一种简单、低成本且传统的方法,可直接利用生物模板在薄膜上制备大面积亚波长抗反射纳米结构。具体而言,通过复制成型技术,蝉翼表面的纳米乳头阵列已被精确复制到聚甲基丙烯酸甲酯(PMMA)薄膜上,具有高重现性,该技术主要涉及两个过程:一是通过热沉积直接从蝉翼生物模板制备负性金模具;二是使用金模具通过浇铸聚合物获得原始蝉翼上纳米结构的复制品。反射光谱测量表明,复制的PMMA薄膜在250至800纳米的大波长范围内可显著降低其表面的反射率,这表明PMMA薄膜也继承了抗反射特性。

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