Department of Gas, Research Institute of Petroleum Industry (RIPI), PO Box 14857-3311, West Boulevard Azadi Sport Complex, Tehran, Iran.
Nanotechnology. 2008 Jun 18;19(24):245612. doi: 10.1088/0957-4484/19/24/245612. Epub 2008 May 9.
Vertically aligned multiwall carbon nanotubes were grown by spray pyrolysis of hexane as the carbon source in the presence of ferrocene as catalyst precursor on a quartz substrate. In recent work we used optimal experimental parameters for the feeding method, reactor conditions, reaction temperature and time, concentration of catalyst and flow rate of feed and gas. The process parameters were chosen so as to obtain multiwall carbon nanotubes and aligned multiwall carbon nanotubes. The tubes are around 15-80 nm in diameter. The morphology and structure of the samples were characterized by x-ray diffraction, Raman spectroscopy, scanning electron microscopy, and transmission electron microscopy analyses.
采用六烷作为碳源,二茂铁作为催化剂前体,通过喷雾热解在石英衬底上垂直生长多壁碳纳米管。在最近的工作中,我们使用了最佳的实验参数,包括进料方式、反应器条件、反应温度和时间、催化剂浓度以及进料和气体流速。选择这些工艺参数是为了获得多壁碳纳米管和定向排列的多壁碳纳米管。这些纳米管的直径约为 15-80nm。通过 X 射线衍射、拉曼光谱、扫描电子显微镜和透射电子显微镜分析对样品的形貌和结构进行了表征。