Department of Pharmacy, University of Tartu, Tartu, Estonia.
Nat Prod Res. 2012;26(13):1173-8. doi: 10.1080/14786419.2010.535154. Epub 2011 Aug 9.
Variations in the essential oil composition of Foeniculum vulgare Mill. commercial fruits obtained from retail pharmacies in Estonia, Norway, Austria and Moldova and from a spice shop in Turkey were determined using capillary GC techniques. The essential oil content of all the samples was 5-51 mL kg(-1) and between 22 and 51 mL kg(-1) in fennel fruits bought from pharmacies. A total of 34 compounds were identified. The major component was trans-anethole (34.8-82.0%); the other principal compounds in oils were fenchone (1.6-22.8%), estragole (2.4-17.0%), limonene (0.8-16.5%), and cis-anethole (0.1-8.6%). The yield of essential oil (5.0 mL kg(-1)) and content of trans-anethole was very low (34.8%) in the Turkish spice sample. Maximum yield of essential oil was found in fennel from Norway and Austria (50.7 and 50.5 mL kg(-1), respectively); these samples were rich in fenchone (21.2% and 22.8%), but contained less trans-anethole (64.6-63.7) than samples from Estonia and Moldova (82.0% and 80.9%). The typical samples of sweet fennel (bought from Estonia and Moldova) and bitter fennel (from Norway and Austria) were found to conform completely or partially to EP standards, although fennel type was always not marked on the packages.
使用毛细管 GC 技术测定了来自爱沙尼亚、挪威、奥地利和摩尔多瓦的零售药店以及土耳其的香料店的商业果实的茴香精油成分的变化。所有样品的精油含量为 5-51 mL/kg,而从药店购买的茴香果实的精油含量在 22-51 mL/kg 之间。总共鉴定出 34 种化合物。主要成分是反式茴香脑(34.8-82.0%);油中的其他主要成分是葑酮(1.6-22.8%)、黄樟素(2.4-17.0%)、柠檬烯(0.8-16.5%)和顺式茴香脑(0.1-8.6%)。土耳其香料样品的精油收率(5.0 mL/kg)和反式茴香脑含量非常低(34.8%)。挪威和奥地利的茴香精油收率最高(分别为 50.7 和 50.5 mL/kg);这些样品富含葑酮(21.2%和 22.8%),但反式茴香脑含量较低(64.6-63.7),而爱沙尼亚和摩尔多瓦的样品中含量较高(82.0%和 80.9%)。发现典型的甜茴香(购自爱沙尼亚和摩尔多瓦)和苦茴香(购自挪威和奥地利)完全或部分符合 EP 标准,尽管包装上始终没有标明茴香类型。