用电化学方法控制铕（III）配合物和紫罗精衍生物的发射和显色。
Electrochemically controllable emission and coloration by using europium(III) complex and viologen derivatives.
机构信息
Graduate School of Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba, Japan.
出版信息
Chem Commun (Camb). 2011 Sep 28;47(36):10064-6. doi: 10.1039/c1cc13855c. Epub 2011 Aug 9.
PMID:21829803
Abstract
We have demonstrated electroswitchable emission and coloration using a novel composite material containing luminescent europium(III) complex Eu(hfa)(3)(H(2)O)(2) and diheptyl viologen HV(2+). The photoluminescence of the Eu(III) complex was controlled by the electrochemical coloration of HV(2+)via intermolecular energy transfer mechanisms.
摘要
我们使用一种新型复合材料，其中包含发光铕（III）配合物 Eu(hfa)(3)(H(2)O)(2)和二庚基紫罗精 HV(2+)，展示了电致变色发光和变色现象。通过分子间能量转移机制，Eu(III)配合物的光致发光可通过 HV(2+)的电化学变色来控制。
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