电化学池中的快速响应和高可逆性的电致变色和发射的电切换。
Electroswitching of emission and coloration with quick response and high reversibility in an electrochemical cell.
机构信息
Department of Image and Materials Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
出版信息
Chem Asian J. 2012 Nov;7(11):2551-4. doi: 10.1002/asia.201200731. Epub 2012 Sep 14.
No fade to grey: Electroswitching of emission and coloration was achieved for a combination of a luminescent Eu(III) complex and an electrochromic molecule of diheptyl viologen (HV(2+)), indicating that such a combination could be used as a display material with dual emissive and reflective modes. The Prussian blue (PB)-modified electrode improved the response time and reversibility for the switching of emission and coloration, by acting as a counter electrode for the electrochromism of HV(2+).
永不褪色的绚丽
通过将发光 Eu(III)配合物与二己基紫罗精（HV(2+)）电致变色分子相结合，实现了发射和显色的电切换，表明这种组合可以用作具有双发射和反射模式的显示材料。普鲁士蓝 (PB) 修饰电极可用作 HV(2+)电致变色的对电极，从而改善了发射和显色切换的响应时间和可逆性。
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