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一种新型钼席夫碱配合物：甲醇[N'-(3-甲氧基-2-氧化苄叉基)苯甲酰肼基]二氧代钼(VI)

A new Mo Schiff base complex: methanol[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]dioxido-molybdenum(VI).

作者信息

Sheikhshoaie Iran, Langer Vratislav, Yasrebi Seyed Ali

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m839-40. doi: 10.1107/S1600536811020101. Epub 2011 Jun 4.

DOI:10.1107/S1600536811020101
PMID:21836845
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3152014/
Abstract

In the title benzil-idene Schiff base molybdenum(VI) complex, [Mo(C(15)H(12)N(2)O(3))O(2)(CH(3)OH)], the Mo(VI) ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N'-(3-meth-oxy-2-oxidobenzyl-idene)benzo-hydrazidate (L) Schiff base ligand. The methanol O atom completes the distorted octa-hedral configuration of the Mo(VI) atom. Strong O-H⋯N hydrogen bonds form a C(5) chain around a 2(1) screw axis. Weak C-H-O hydrogen bonds are also present.

摘要

在标题化合物亚苄基席夫碱钼（VI）配合物[Mo(C₁₅H₁₂N₂O₃)O₂(CH₃OH)]中，Mo(VI)离子由两个氧化物O原子以及三齿N'-(3-甲氧基-2-氧化亚苄基)苯肼酸酯（L）席夫碱配体的两个O原子和一个N原子配位。甲醇的O原子完善了Mo(VI)原子的畸变八面体构型。强O—H⋯N氢键围绕2(1)螺旋轴形成C(5)链。同时还存在弱C—H—O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/e0798b40a6ce/e-67-0m839-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/ec913b92a90f/e-67-0m839-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/5508187c2a17/e-67-0m839-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/e0798b40a6ce/e-67-0m839-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/ec913b92a90f/e-67-0m839-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/5508187c2a17/e-67-0m839-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2292/3152014/e0798b40a6ce/e-67-0m839-fig3.jpg

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