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[(N'-(3-乙氧基-2-氧化苄叉基)-4-羟基-3-甲氧基苯甲酰肼基](甲醇)二氧钼(VI)

[N'-(3-Eth-oxy-2-oxidobenzyl-idene)-4-hy-droxy-3-meth-oxy-benzohydrazidato](methanol)dioxidomolybdenum(VI).

作者信息

Wang Shou-Xing

机构信息

Laboratory Management Center, Zaozhuang University, Zaozhuang 277160, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m358-9. doi: 10.1107/S1600536812008549. Epub 2012 Mar 3.

Abstract

In the title dioxidomolybdenum(VI) complex, [Mo(C(17)H(16)N(2)O(5))O(2)(CH(3)OH)], the Mo(VI) atom is coordinated by the phenolate O, imine N and enolic O atoms of the tridentate hydrazone ligand, one methanol O atom, and two oxide O atoms, forming a distorted octa-hedral coordination geometry. The oxide O atoms adopt a cis conformation: one is trans to the methanol O atom and the other is trans to the ligand N atom. The dihedral angle between the two benzene rings in the hydrazone ligand is 4.0 (3)°. In the crystal, mol-ecules are linked by O-H⋯N and O-H⋯O hydrogen bonds.

摘要

在标题化合物二氧代钼(VI)配合物[Mo(C₁₇H₁₆N₂O₅)O₂(CH₃OH)]中,Mo(VI)原子由三齿腙配体的酚氧原子、亚胺氮原子和烯醇氧原子、一个甲醇氧原子以及两个氧化物氧原子配位,形成扭曲的八面体配位几何构型。氧化物氧原子呈顺式构象:一个与甲醇氧原子相对,另一个与配体氮原子相对。腙配体中两个苯环之间的二面角为4.0 (3)°。在晶体中,分子通过O—H⋯N和O—H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/29bb/3343783/250bc088764d/e-68-0m358-fig1.jpg

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