Zhang Xiao-Wen, Fan Ting
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m875. doi: 10.1107/S1600536811021039. Epub 2011 Jun 11.
In the title compound, [Bi(C(20)H(17)N)(ClO(4))] or C(20)H(17)BiClNO(4), the Bi(III) ion assumes a distorted ψ trigonal-bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure.
在标题化合物[Bi(C₂₀H₁₇N)(ClO₄)]或C₂₀H₁₇BiClNO₄中，Bi(III)离子呈扭曲的ψ三角双锥几何构型，两个C原子和Bi原子的电子孤对位于赤道位置，一个胺N原子和一个高氯酸根O原子位于顶点位置。晶体结构中存在弱的分子间C—H⋯O氢键。
