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6-环己基-6,7-二氢-二苯并[c,f][1,5]氮杂双辛因-12(5H)-基（N→Bi）三氟甲磺酸盐

6-Cyclo-hexyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl(N→Bi) trifluoro-methane-sulfonate.

作者信息

Tan Nianyuan, Zhang Xiaowen

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m252. doi: 10.1107/S1600536811002510.

DOI:10.1107/S1600536811002510
PMID:21522906
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3051572/
Abstract

In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal-bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo-hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14).

摘要

在标题化合物[Bi(C₂₀H₂₃N)(CF₃SO₃)]中，Bi(III)离子呈现出扭曲的假三角双锥几何构型，两个C原子和Bi原子的一对孤电子对处于赤道位置，N和O原子处于顶点位置。环己基在两种取向间无序分布，占位因子分别为0.600 (14)和0.400 (14)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/045f/3051572/2a1414c75f11/e-67-0m252-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/045f/3051572/2a1414c75f11/e-67-0m252-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/045f/3051572/2a1414c75f11/e-67-0m252-fig1.jpg

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