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链状聚[[[水合双(4,4'-联吡啶-κN)锌]-μ-L-酪氨酸根合-κN,O:O]硝酸二水合物]

catena-Poly[[[aqua-bis-(4,4'-bipyridine-κN)zinc]-μ-l-tyrosinato-κN,O:O] nitrate dihydrate].

作者信息

Li Shu-Qiang, Hu Ning-Hai

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m884-5. doi: 10.1107/S1600536811021088. Epub 2011 Jun 11.

Abstract

In the title compound, {[Zn(C(9)H(10)NO(3))(C(10)H(8)N(2))(2)(H(2)O)]NO(3)·2H(2)O}(n), the Zn(II) atom is six-coordinated in a distorted octa-hedral geometry by two carboxyl-ate O atoms and one amino N atom from two l-tyrosinate ligands, two N atoms from two 4,4'-bipyridine ligands, and one water mol-ecule. Adjacent Zn atoms are bridged by the bidentate carboxyl-ate groups into a cationic chain extending along [010]. N-H⋯N, O-H⋯N and O-H⋯O hydrogen bonds link the cationic chains, nitrate anions and uncoordinated water mol-ecules into a supra-molecular network. π-π inter-actions between the pyridine rings and between the pyridine and benzene rings [centroid-centroid distances = 3.615 (4) and 3.636 (4) Å] are present.

摘要

在标题化合物{[Zn(C₉H₁₀NO₃)(C₁₀H₈N₂)₂(H₂O)]NO₃·2H₂O}ₙ中,Zn(II)原子由来自两个L-酪氨酸根配体的两个羧酸根O原子、一个氨基N原子、来自两个4,4'-联吡啶配体的两个N原子以及一个水分子以扭曲的八面体几何构型进行六配位。相邻的Zn原子通过双齿羧酸根基团桥连形成沿[010]方向延伸的阳离子链。N-H⋯N、O-H⋯N和O-H⋯O氢键将阳离子链、硝酸根阴离子和未配位的水分子连接成一个超分子网络。吡啶环之间以及吡啶环与苯环之间存在π-π相互作用[质心-质心距离 = 3.615 (4) 和3.636 (4) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a47a/3152081/f583bdb5f737/e-67-0m884-fig1.jpg

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