Liu Shi-Yong, Wang Xiao-Ling
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1625. doi: 10.1107/S1600536811020769. Epub 2011 Jun 11.
In the hydrazone mol-ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol-ecules are involved in the formation of inter-molecular N-H⋯O and O-H⋯N hydrogen bonds, which link the mol-ecules into double ribbons extending along the b axis. Inter-molecular π-π inter-actions between the aromatic rings [centroid-centroid distances = 3.712 (3) and 3.672 (3) Å] link these ribbons further into layers parallel to the ab plane.
在标题化合物C(15)H(12)ClN(3)O(4)·H(2)O的腙分子中,两个苯环形成的二面角为3.6 (1)°。在晶体结构中,溶剂水分子参与形成分子间的N-H⋯O和O-H⋯N氢键,这些氢键将分子连接成沿b轴延伸的双链。芳香环之间的分子间π-π相互作用[质心-质心距离 = 3.712 (3) 和3.672 (3) Å]将这些双链进一步连接成平行于ab平面的层。