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(E)-4-甲氧基-N'-(4-硝基亚苄基)苯甲酰肼甲醇单溶剂合物

(E)-4-Meth-oxy-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

作者信息

Ban Hong-Yan

机构信息

School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):o3240. doi: 10.1107/S160053681004701X.

Abstract

The hydrazone mol-ecule of the title compound, C(15)H(13)N(3)O(4)·CH(4)O, is nearly planar, with a dihedral angle between the two benzene rings of 1.2 (4)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, the benzohydrazide and methanol mol-ecules are linked through inter-molecular O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds, forming chains along the a axis.

摘要

标题化合物C(15)H(13)N(3)O(4)·CH(4)O的腙分子近乎平面,两个苯环之间的二面角为1.2 (4)°。该分子相对于中心亚甲基单元呈反式构型。在晶体中,苯甲酰肼和甲醇分子通过分子间的O-H⋯O、O-H⋯N和N-H⋯O氢键相连,沿a轴形成链状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e638/3011623/3376f39cb8ef/e-66-o3240-fig1.jpg

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