9-(3-溴-5-氯-2-羟基苯基)-10-(2-羟基乙基)-3,6-二苯基-3,4,9,10-四氢吖啶-1,8(2H,5H)-二酮
9-(3-Bromo-5-chloro-2-hy-droxy-phen-yl)-10-(2-hy-droxy-eth-yl)-3,6-diphenyl-3,4,9,10-tetra-hydro-acridine-1,8(2H,5H)-dione.
作者信息
Akkurt Mehmet, Mohamed Shaaban K, Abdelhamid Antar A, Gaber Abdel-Aal M, Albayati Mustafa R
机构信息
Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey.
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 May 17;70(Pt 6):o663-4. doi: 10.1107/S1600536814010460. eCollection 2014 Jun 1.
In the title compound, C33H27BrClNO4, the di-hydro-pyridine ring adopts a flattened boat conformation. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond, with an S(8) ring motif. In the crystal, O-H⋯O, C-H⋯O and C-H⋯Cl hydrogen bonds, and C-H⋯π inter-actions link the mol-ecules, forming a three-dimensional network. In the acridinedione ring system, the two ring C atoms at the 2- and 3-positions, and the C atom at the 6-position and the atoms of the phenyl ring attached to the C atom at the 6-position are disordered over two sets of sites with occupancy ratios of 0.783 (5):0.217 (5) and 0.526 (18):0.474 (18), respectively.
在标题化合物C₃₃H₂₇BrClNO₄中，二氢吡啶环呈扁平船式构象。分子构象通过分子内O—H⋯O氢键得以稳定，形成S(8)环模式。在晶体中，O—H⋯O、C—H⋯O和C—H⋯Cl氢键以及C—H⋯π相互作用将分子连接起来，形成三维网络。在吖啶二酮环系中，2-和3-位的两个环碳原子、6-位的碳原子以及连接在6-位碳原子上的苯环原子在两组位置上无序排列，占有率分别为0.783 (5):0.217 (5)和0.526 (18):0.474 (18)。
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