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N,N-双(4-甲氧基-亚苄基)-3,3'-二甲基联苯胺

N,N-Bis(4-meth-oxy-benzyl-idene)-3,3'-dimethyl-benzidine.

作者信息

Wang Juangang, Yang Peipei, Yang Jin

机构信息

College of Chemistry and Material Science, Huaibei Normal University, Xiangshan, Huaibei 235000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1753. doi: 10.1107/S1600536811023749. Epub 2011 Jun 22.

Abstract

The mol-ecule of the title compund, C(30)H(28)N(2)O(2), a Schiff base synthesised via a condensation reaction between 4-meth-oxy-benzaldehyde and 3,3'-dimethyl-benzidine, a crystallographic twofold rotation axis passes through the mid-point of the C-C bond of the biphenyl unit. Thus, the asymmetric unit comprises one half-mol-ecule. In the biphenyl unit, the aromatic rings are twisted by 13.49 (7)° with respect to one another. The dihedral angles between the biphenyl and meth-oxy-benzene rings are 49.95 (12) and 50.06 (12)°. In the crystal, weak inter-molecular C-H⋯ O hydrogen bonds contribute to the stabilization of the packing.

摘要

标题化合物C(30)H(28)N(2)O(2)是一种席夫碱,通过4-甲氧基苯甲醛与3,3'-二甲基联苯胺之间的缩合反应合成。一个晶体学二重旋转轴穿过联苯单元C-C键的中点。因此,不对称单元包含半个分子。在联苯单元中,芳环彼此扭转了13.49 (7)°。联苯环与甲氧基苯环之间的二面角分别为49.95 (12)°和50.06 (12)°。在晶体中,弱的分子间C-H⋯O氢键有助于稳定堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/865f/3152131/f20b25c7d493/e-67-o1753-fig1.jpg

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