• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

糖唑利啶

Glycozolidal.

作者信息

Fun Hoong-Kun, Maneerat Wisanu, Laphookhieo Surat, Chantrapromma Suchada

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1811-2. doi: 10.1107/S1600536811024160. Epub 2011 Jun 25.

DOI:10.1107/S1600536811024160
PMID:21837182
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3151865/
Abstract

THE TITLE COMPOUND KNOWN AS GLYCOZOLIDAL (SYSTEMATIC NAME: 2,7-dimeth-oxy-9H-carbazole-3-carbaldehyde), C(15)H(13)NO(3), is a naturally occurring carbazole, which was isolated from the roots of Clausena lansium. The carbazole ring system is essentially planar, with an r.m.s. deviation of 0.0093 (1) Å. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the mol-ecules into a chain along the c axis. C-H⋯O, C-H⋯π and π-π inter-actions, with centroid-centroid distances of 3.5924 (6), 3.6576 (6) and 3.8613 (6) Å, are also observed.

摘要

标题化合物称为糖唑（系统名称：2,7 - 二甲氧基 - 9H - 咔唑 - 3 - 甲醛），化学式为C(15)H(13)NO(3)，是一种天然存在的咔唑，从黄皮树的根中分离得到。咔唑环系统基本呈平面状，均方根偏差为0.0093 (1) Å。在晶体中，分子间的N - H⋯O氢键将分子沿c轴连接成链。还观察到C - H⋯O、C - H⋯π和π - π相互作用，质心 - 质心距离分别为3.5924 (6)、3.6576 (6)和3.8613 (6) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2c3/3151865/0afab0c5ebf3/e-67-o1811-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2c3/3151865/512c1256ec61/e-67-o1811-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2c3/3151865/0afab0c5ebf3/e-67-o1811-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2c3/3151865/512c1256ec61/e-67-o1811-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f2c3/3151865/0afab0c5ebf3/e-67-o1811-fig2.jpg

相似文献

1
Glycozolidal.糖唑利啶
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1811-2. doi: 10.1107/S1600536811024160. Epub 2011 Jun 25.
2
Indizoline.吲唑啉
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 19;65(Pt 10):o2497-8. doi: 10.1107/S1600536809036915.
3
Crystal structures of three carbazole derivatives: 12-ethyl-7-phenyl-sulfonyl-7-benzofuro[2,3-]carbazole, (1), 2-(4,5-dimeth-oxy-2-nitro-phen-yl)-4-hy-droxy-9-phenyl-sulfonyl-9-carbazole-3-carbaldehyde, (2), and 12-phenyl-7-phenyl-sulfonyl-7-benzofuro[2,3-]carbazole, (3).三种咔唑衍生物的晶体结构：12-乙基-7-苯基磺酰基-7-苯并呋喃并[2,3-]咔唑，（1）；2-（4,5-二甲氧基-2-硝基苯基）-4-羟基-9-苯基磺酰基-9-咔唑-3-甲醛，（2）；以及12-苯基-7-苯基磺酰基-7-苯并呋喃并[2,3-]咔唑，（3）。
Acta Crystallogr E Crystallogr Commun. 2016 Nov 4;72(Pt 12):1744-1750. doi: 10.1107/S2056989016016819. eCollection 2016 Dec 1.
4
2-(4,5-Dimeth-oxy-2-nitro-phen-yl)-4-meth-oxy-9-phenyl-sulfonyl-9H-carbazole-3-carbaldehyde.2-（4,5-二甲氧基-2-硝基苯基）-4-甲氧基-9-苯基磺酰基-9H-咔唑-3-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 12;70(Pt 4):o424-5. doi: 10.1107/S1600536814005133. eCollection 2014 Apr 1.
5
Crystal structure and luminescence properties of 2-[(2',6'-dimeth-oxy-2,3'-bipyridin-6-yl)-oxy]-9-(pyridin-2-yl)-9-carbazole.2-[(2',6'-二甲氧基-2,3'-联吡啶-6-基)-氧基]-9-(吡啶-2-基)-9-咔唑的晶体结构与发光性质
Acta Crystallogr E Crystallogr Commun. 2019 Oct 22;75(Pt 11):1646-1649. doi: 10.1107/S2056989019013549. eCollection 2019 Nov 1.
6
Crystal structures of two new carbazole derivatives: 12-(4-nitro-phen-yl)-7-phenyl-sulfonyl-7-benzofuro[2,3-]carbazole and 2-methyl-4-(4-nitro-phen-yl)-9-phenyl-sulfonyl-9-thieno[2,3-]carbazole.两种新型咔唑衍生物的晶体结构：12-(4-硝基苯基)-7-苯基磺酰基-7-苯并呋喃并[2,3-]咔唑和2-甲基-4-(4-硝基苯基)-9-苯基磺酰基-9-噻吩并[2,3-]咔唑。
Acta Crystallogr E Crystallogr Commun. 2016 Nov 4;72(Pt 12):1739-1743. doi: 10.1107/S2056989016016996. eCollection 2016 Dec 1.
7
2-Hy-droxy-7-meth-oxy-9H-carbazole-3-carbaldehyde.2-羟基-7-甲氧基-9H-咔唑-3-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):o2418-9. doi: 10.1107/S1600536810033805.
8
Vieillardiixanthone B.维耶拉地蒽酮B
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 13;66(Pt 4):o817-8. doi: 10.1107/S1600536810007026.
9
Ethyl 4-hydr-oxy-9-tosyl-9H-carbazole-3-carboxyl-ate.4-羟基-9-对甲苯磺酰基-9H-咔唑-3-羧酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1515-6. doi: 10.1107/S1600536809021035.
10
N-(2,6-Dimeth-oxy-pyridin-3-yl)-9-methyl-9H-carbazole-3-sulfonamide.N-（2,6-二甲氧基吡啶-3-基）-9-甲基-9H-咔唑-3-磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 23;69(Pt 4):o584. doi: 10.1107/S1600536813007460. Print 2013 Apr 1.

引用本文的文献

1
Cytotoxicity and Apoptosis Induction of Coumarins and Carbazole Alkaloids from .香豆素和咔唑生物碱对. 的细胞毒性和细胞凋亡诱导作用
Molecules. 2019 Sep 18;24(18):3385. doi: 10.3390/molecules24183385.

本文引用的文献

1
2-Hy-droxy-7-meth-oxy-9H-carbazole-3-carbaldehyde.2-羟基-7-甲氧基-9H-咔唑-3-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):o2418-9. doi: 10.1107/S1600536810033805.
2
Indizoline.吲唑啉
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 19;65(Pt 10):o2497-8. doi: 10.1107/S1600536809036915.
3
Carbazole alkaloids from the stems of Clausena excavata.从黄皮茎中提取的咔唑生物碱。
J Asian Nat Prod Res. 2010 Jul;12(7):614-7. doi: 10.1080/10286020.2010.482524.
4
Biological activity of chemical constituents from Clausena harmandiana.哈曼当归化学成分的生物活性。
Arch Pharm Res. 2010 May;33(5):675-80. doi: 10.1007/s12272-010-0505-x. Epub 2010 May 29.
5
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
6
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
7
Coumarins and carbazoles with antiplasmodial activity from Clausena harmandiana.来自大叶山小橘的具有抗疟活性的香豆素和咔唑类化合物。
Planta Med. 2000 Apr;66(3):277-9. doi: 10.1055/s-2000-8558.