Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
J Org Chem. 2011 Sep 16;76(18):7563-8. doi: 10.1021/jo201174r. Epub 2011 Aug 24.
A cobalt-bathophenanthroline catalyst has been developed for the direct preparation of a variety of arylindium reagents from the corresponding aryl and heteroaryl bromides in the presence of indium metal and lithium chloride. The thus-formed arylindium reagents undergo efficient palladium-catalyzed cross-coupling reactions with aryl iodides, tolerating various functional groups including hydroxy and free amino groups.
一种钴-邻菲啰啉催化剂已被开发出来，用于在铟金属和氯化锂的存在下，直接从相应的芳基和杂芳基溴化物制备各种芳基铟试剂。形成的芳基铟试剂与芳基碘化物发生高效的钯催化交叉偶联反应，可耐受包括羟基和游离氨基在内的各种官能团。
