铑催化的酚类衍生物的直接邻位 C-H 烯烃化反应。
Rhodium-catalyzed direct ortho C-H olefination of phenol derivatives.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637616.
出版信息
Chem Commun (Camb). 2011 Oct 7;47(37):10458-60. doi: 10.1039/c1cc14108b. Epub 2011 Aug 18.
PMID:21850318
Abstract
Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an α,β-unsaturated ester appendage is described. In addition, deuterium labelling and kinetic isotope effect studies were performed to probe the reaction mechanism.
摘要
本文描述了铑阳离子配合物催化酚类衍生物的烯烃化反应，可直接引入α,β-不饱和酯侧链。此外，还进行了氘标记和动力学同位素效应研究，以探讨反应机理。
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