Department of Physics and Astronomy, Clemson University, Clemson, SC 29634, USA.
J Phys Condens Matter. 2011 Sep 14;23(36):365802. doi: 10.1088/0953-8984/23/36/365802. Epub 2011 Aug 19.
We develop a phenomenological theory for cross-plane transport in a semiconductor superlattice (SL) doped with nanostructures to improve the thermoelectric properties. The SL consists of an array of quantum wells equally spaced along a spatial direction separated by narrow barriers, such that, in the presence of inter-well tunneling, a miniband energy structure is established. The semi-metallic ErAs nanoparticles are embedded inside the quantum wells in the process of growth of the SL, as reported in several recent experiments. Their effect on thermoelectric transport is considered through an additional contribution to the electron scattering rate, that is correlated with a process of resonant tunneling through the nanoparticle-semiconductor interface modeled as a Schottky barrier. In a semi-classical approximation of the miniband conduction regime, we calculate the electric conductivity, the thermopower and the power factor as a function of the barrier height and demonstrate the presence of a filtering effect, whereby the Seebeck coefficient is enhanced by the additional scattering.
我们为掺杂纳米结构的半导体超晶格(SL)开发了一种用于横平面输运的唯象理论,以改善其热电性能。该 SL 由沿空间方向等距排列的量子阱组成,由狭窄的势垒隔开,使得在阱间隧穿存在的情况下,建立了一个能隙结构。半金属 ErAs 纳米粒子在 SL 的生长过程中被嵌入到量子阱中,这在最近的一些实验中得到了报道。通过对电子散射率的额外贡献来考虑它们对热输运的影响,这与通过纳米粒子-半导体界面的共振隧穿过程相关联,该过程被建模为肖特基势垒。在能带输运的半经典近似中,我们计算了电导率、塞贝克系数和功率因子作为势垒高度的函数,并证明了存在滤波效应,其中通过额外散射增强了 Seebeck 系数。