Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.
Chem Commun (Camb). 2011 Oct 14;47(38):10827-9. doi: 10.1039/c1cc14602e. Epub 2011 Aug 24.
A new tert-butyl peresters synthesis directly from aldehydes and TBHP was developed via Bu(4)NI-catalyzed aldehyde C-H oxidation. Mechanistic studies suggest that the protocol proceeds via a radical process. Combining the method with the Kharasch-Sosnovsky reaction offers a practical approach for the synthesis of allylic esters from simple aldehydes and alkenes via a two-step one-pot procedure.
通过 Bu(4)NI 催化的醛 C-H 氧化，开发了一种从醛和 TBHP 直接合成新的叔丁基过酸酯的方法。机理研究表明，该反应通过自由基历程进行。该方法与 Kharasch-Sosnovsky 反应相结合，为通过两步一锅法从简单醛和烯烃合成烯丙基酯提供了一种实用方法。
