Bu4NI 催化的芳基醛与烷基芳烃的苄基酰氧化反应。

Bu4NI-catalyzed benzylic acyloxylation of alkylarenes with aromatic aldehydes.

机构信息

State Key Laboratory of Medicinal Chemical Biology, College of Pharmacy, Nankai University, 94 Weijin Road, Tianjin 300071, China.

出版信息

Chem Commun (Camb). 2012 Oct 21;48(82):10204-6. doi: 10.1039/c2cc35450k.

DOI:10.1039/c2cc35450k

PMID:22968182

Abstract

An nBu(4)NI-catalyzed benzylic C-H acyloxylation of alkylarenes with readily available aromatic aldehydes has been developed. These reactions occur under mild and clean reaction conditions using tert-butyl hydroperoxide as the green terminal oxidant.

摘要

一种 nBu(4)NI 催化的、带有易获得的芳基醛的苄基 C-H 酰氧基化反应已被开发出来。这些反应在温和且清洁的反应条件下进行，使用叔丁基过氧化氢作为绿色末端氧化剂。