Universitat Rovira i Virgili, Departament de Química Física i Inorgánica, Campus Sescelades, C/Marcel·lí Domingo s/n, 43007, Tarragona, Spain.
Chem Soc Rev. 2011 Oct;40(10):4973-85. doi: 10.1039/c1cs15195a. Epub 2011 Aug 30.
The catalytic formation of C-C bonds is one of the most useful transformations in organic synthesis. Over the last decade, the use of transition metal nanoparticles (NPs) in catalysis has attracted much interest and their use in C-C bond formation reactions constitutes one of their most important applications, including the Suzuki, Heck, and Sonogashira reactions. This tutorial review highlights recent work in this active area, considering the stabilising agents used to prepare the NPs, the catalytic results and the recycling possibilities.
C-C 键的催化形成是有机合成中最有用的转化之一。在过去的十年中，过渡金属纳米粒子 (NPs) 在催化中的应用引起了极大的关注，它们在 C-C 键形成反应中的应用是其最重要的应用之一，包括 Suzuki、Heck 和 Sonogashira 反应。本综述强调了该活跃领域的最新工作，考虑了用于制备 NPs 的稳定剂、催化结果和回收可能性。
