Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China.
Chem Commun (Camb). 2011 Oct 14;47(38):10632-4. doi: 10.1039/c1cc14591f. Epub 2011 Sep 5.
Planar chiral nucleophilic catalyst Fc-PIP was employed in the kinetic resolution of bulky (hetero)arylalkyl carbinols delivering unreacted alcohols with extremely high enantiomeric excess (>99.0% ees) in ideal conversions ranging from 50.4-56.7%.
手性亲核催化剂 Fc-PIP 被用于动力学拆分大位阻（杂）芳基烷基醇，未反应的醇以理想的转化率 (>99.0%ee) 获得极高的对映过量 (>99.0%ee)。
