Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UJF-UPS-INSA, 38042 Grenoble, France.
Nature. 2011 Sep 7;477(7363):191-4. doi: 10.1038/nature10345.
Electronic charges introduced in copper-oxide (CuO(2)) planes generate high-transition-temperature (T(c)) superconductivity but, under special circumstances, they can also order into filaments called stripes. Whether an underlying tendency towards charge order is present in all copper oxides and whether this has any relationship with superconductivity are, however, two highly controversial issues. To uncover underlying electronic order, magnetic fields strong enough to destabilize superconductivity can be used. Such experiments, including quantum oscillations in YBa(2)Cu(3)O(y) (an extremely clean copper oxide in which charge order has not until now been observed) have suggested that superconductivity competes with spin, rather than charge, order. Here we report nuclear magnetic resonance measurements showing that high magnetic fields actually induce charge order, without spin order, in the CuO(2) planes of YBa(2)Cu(3)O(y). The observed static, unidirectional, modulation of the charge density breaks translational symmetry, thus explaining quantum oscillation results, and we argue that it is most probably the same 4a-periodic modulation as in stripe-ordered copper oxides. That it develops only when superconductivity fades away and near the same 1/8 hole doping as in La(2-x)Ba(x)CuO(4) (ref. 1) suggests that charge order, although visibly pinned by CuO chains in YBa(2)Cu(3)O(y), is an intrinsic propensity of the superconducting planes of high-T(c) copper oxides.
电子电荷在氧化铜(CuO(2))平面中引入,产生高温超导性,但在特殊情况下,它们也可以有序排列成称为条纹的细丝。然而,在所有的铜氧化物中是否存在潜在的电荷有序倾向,以及这种倾向是否与超导性有关,这两个问题是高度争议的。为了揭示潜在的电子有序性,可以使用足以破坏超导性的强磁场。包括在 YBa(2)Cu(3)O(y)(一种非常干净的铜氧化物,到目前为止还没有观察到电荷有序)中的量子振荡等实验表明,超导性与自旋有序而不是电荷有序竞争。在这里,我们报告了核磁共振测量结果,表明在 YBa(2)Cu(3)O(y)的 CuO(2)平面中,强磁场实际上会在没有自旋有序的情况下诱导电荷有序。观察到的电荷密度的静态、单向调制打破了平移对称性,从而解释了量子振荡结果,我们认为它很可能与条纹有序的铜氧化物中的相同的 4a 周期调制。只有当超导性消失,并且在与 La(2-x)Ba(x)CuO(4)(参考文献 1)相同的 1/8 空穴掺杂时,电荷有序才会发展,这表明尽管在 YBa(2)Cu(3)O(y)中,电荷有序被 CuO 链明显固定,但它是高温铜氧化物超导平面的内在倾向。