手性水杨醛席夫碱多金属氧酸盐衍生物的不对称催化和光催化活性。
Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities.
机构信息
Institute of Functional Materials, Department of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China.
出版信息
Dalton Trans. 2011 Oct 21;40(39):9964-6. doi: 10.1039/c1dt11227a. Epub 2011 Sep 9.
PMID:21904746
Abstract
Immobilization of the chiral salen-metal complex [Mn(III)(salen)(H(2)O)(2)ClO(4)] on the Keggin-type polyoxometalate (POM) skeletons leads to the isolation of POM derivatives functionalized with chiral salen-metal complexes, which represent the first examples of introducing chiral salen-metal complexes into the POM systems.
摘要
将手性 salen-金属配合物[Mn(III)(salen)(H(2)O)(2)ClO(4)]固定在 Keggin 型多金属氧酸盐(POM)骨架上，得到了功能化的手性 salen-金属配合物的 POM 衍生物，这代表了首次将手性 salen-金属配合物引入 POM 体系。
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