Institute of Functional Materials, Department of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China.
Dalton Trans. 2011 Oct 21;40(39):9964-6. doi: 10.1039/c1dt11227a. Epub 2011 Sep 9.
Immobilization of the chiral salen-metal complex [Mn(III)(salen)(H(2)O)(2)ClO(4)] on the Keggin-type polyoxometalate (POM) skeletons leads to the isolation of POM derivatives functionalized with chiral salen-metal complexes, which represent the first examples of introducing chiral salen-metal complexes into the POM systems.
将手性 salen-金属配合物[Mn(III)(salen)(H(2)O)(2)ClO(4)]固定在 Keggin 型多金属氧酸盐(POM)骨架上，得到了功能化的手性 salen-金属配合物的 POM 衍生物，这代表了首次将手性 salen-金属配合物引入 POM 体系。
