C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, WV 26506, USA.
Phys Chem Chem Phys. 2011 Oct 21;13(39):17802-8. doi: 10.1039/c1cp22109d. Epub 2011 Sep 13.
We investigate the origin and evolution of spatiotemporal complexity in a system of locally coupled Belousov-Zhabotinsky chemical oscillators. Using a combination of high resolution microscopy and fine grain numerical modeling, we demonstrate that the behavior arises from an initial phase heterogeneity of the oscillators. This heterogeneity produces wave breaks in the system with the free ends becoming pinned to holes in the medium. The fastest of these pinned tips behave as reentrant circuits that phase set the rest of the medium. The slower tips are repeatedly destroyed and then re-created by the central circuit. The resulting spatiotemporal pattern repeats with the frequency of the reentrant circuit, with its spatial structure depending on the location of the initial wave breaks.
我们研究了局部耦合 Belousov-Zhabotinsky 化学振荡器系统中时空复杂性的起源和演化。我们使用高分辨率显微镜和细粒度数值建模的组合,证明了这种行为源于振荡器的初始相位不均匀性。这种不均匀性导致了系统中的波破裂,自由端被固定在介质中的孔上。其中最快的固定尖端表现为折返电路,使介质的其余部分相位同步。较慢的尖端则被中央电路反复破坏和重建。由此产生的时空模式以折返电路的频率重复出现,其空间结构取决于初始波破裂的位置。