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多壁碳纳米管锚定在 SnS2 纳米片上作为锂离子电池的高性能阳极材料。

Multiwalled carbon nanotubes anchored with SnS2 nanosheets as high-performance anode materials of lithium-ion batteries.

机构信息

State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2011 Oct;3(10):4067-74. doi: 10.1021/am200933m. Epub 2011 Sep 22.

Abstract

A nanocomposite of multiwalled carbon nanotubes (MWCNTs) anchored with SnS(2) nanosheets (NS) (SnS(2) NS@MWCNTs coaxial nanocables) has been synthesized through a simple solution-based method at room temperature. The synthetic mechanism of these intriguing nanocomposites is proposed as electrostatic attraction between tin ions and MWCNTs, followed by the nucleation and two-dimensional growth of SnS(2). The as-synthesized SnS(2) NS@MWCNTs coaxial nanocables have been applied as anode materials for lithium-ion batteries, which show better lithium storage performance compared to pure SnS(2) nanosheets and MWCNTs. The combination of MWCNTs that can hinder the agglomeration and enhance electronic conductivity of the active materials might be responsible for the enhanced cyclic performance.

摘要

通过一种简单的室温下基于溶液的方法,合成了一种多壁碳纳米管(MWCNTs)锚定的 SnS(2)纳米片(NS)的纳米复合材料(SnS(2) NS@MWCNTs 同轴纳米电缆)。提出了这些有趣的纳米复合材料的合成机制,即锡离子和 MWCNTs 之间的静电吸引,随后是 SnS(2)的成核和二维生长。所合成的 SnS(2) NS@MWCNTs 同轴纳米电缆已被用作锂离子电池的阳极材料,与纯 SnS(2)纳米片和 MWCNTs 相比,其具有更好的锂存储性能。MWCNTs 的结合可以阻止活性材料的团聚并提高其电子导电性,这可能是循环性能得到提高的原因。

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