Departamento de Ingeniería Química, Universidad de Santiago de Chile, Santiago de Chile, Chile.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2011;46(12):1385-91. doi: 10.1080/10934529.2011.606709.
Nitrogen and phosphorus can cause eutrophication problems in receiving waters. These nutrients can be eliminated by different wastewater treatments but they tend to be costly or require complex operations. With these reasons in mind, this work set out to study the behavior of a novel combined or integrated system with zeolite and lime for the removal of these chemical species. With the integrated treatment, excellent removals-98 % NH(+) (4), 100 % total phosphorus (TP), 79 % chemical oxygen demand (COD), 71 % BOD(5), 99 % of total suspended solids (TSS) and 100 % of fecal coliforms-were obtained. A sludge production of 4.4 % and 4.8 % of the wastewater total volume treated with lime was achieved. The final liquid effluent of the integrated system of natural zeolite and lime had a composition which was suitable for its discharge into sewerage systems and marine or continental waters (according to Chilean regulations), as far as the concentrations of nitrogen, phosphorus and total coliforms were concerned. Validated curves with their corresponding equations were obtained in this study for the removal of ammonia nitrogen and total phosphorus. These equations can theoretically be applied to estimate the removal of both parameters in studies or practical applications undertaken with operating conditions similar to those used in this work.
氮和磷会导致受纳水体富营养化问题。这些营养物质可以通过不同的废水处理方法去除,但它们往往成本较高或需要复杂的操作。考虑到这些原因,本工作研究了沸石和石灰的新型组合或集成系统去除这些化学物质的行为。采用集成处理,可获得优异的去除率-98%的氨氮(NH4+)(4)、100%的总磷(TP)、79%的化学需氧量(COD)、71%的五日生化需氧量(BOD5)、99%的总悬浮固体(TSS)和 100%的粪大肠菌群。石灰处理的废水总体积的污泥产量分别为 4.4%和 4.8%。天然沸石和石灰集成系统的最终液体流出物的组成适合排入污水系统和海洋或大陆水域(根据智利法规),就氮、磷和总大肠菌群的浓度而言。本研究获得了去除氨氮和总磷的验证曲线及其相应的方程。这些方程理论上可应用于估计在与本工作中使用的操作条件相似的研究或实际应用中去除这两个参数。