Physical and Life Sciences Directorate, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA.
Nanotechnology. 2011 Oct 28;22(43):435603. doi: 10.1088/0957-4484/22/43/435603. Epub 2011 Oct 3.
Bundles of multi-walled carbon nanotubes of uniform diameter decorated with Ni nanoparticles were synthesized using mesoporous silicates as templates. The ordered morphology and the narrow pore size distribution of mesoporous silicates provide an ideal platform to synthesize uniformly sized carbon nanotubes. In addition, homogeneous sub-10 nm pore sizes of the templates allow in situ formation of catalytic nanoparticles with uniform diameters which end up decorating the carbon nanotubes. The resulting carbon nanotubes are multi-walled with a uniform diameter corresponding to the pore diameter of the template used during the synthesis that are decorated with the catalysts used to synthesize them. They have a narrow size distribution which can be used in many energy related fields of research.
使用介孔硅作为模板合成了具有均匀直径的 Ni 纳米粒子修饰的多壁碳纳米管。介孔硅的有序形态和窄的孔径分布为合成均匀尺寸的碳纳米管提供了理想的平台。此外,模板的均匀亚 10nm 孔径允许催化纳米粒子原位形成,其最终均匀地修饰在碳纳米管上。所得的碳纳米管是多壁的,其直径与合成过程中使用的模板的孔径相对应,并且用用于合成它们的催化剂进行了修饰。它们具有窄的尺寸分布,可用于许多与能源相关的研究领域。