State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Chem Commun (Camb). 2011 Nov 21;47(43):11933-5. doi: 10.1039/c1cc14702a. Epub 2011 Oct 5.
A 3D metal-organic framework, featuring three kinds of cation channels, was obtained through an ionothermal reaction. Investigation on its temperature-dependent conductivity indicates the contribution of order and disorder of the Emim(+) (Emim(+) = 1-ethyl-3-methyl imidazolium bromide) in the channel to its conductivity.
通过离子热反应得到了一种具有三种阳离子通道的三维金属有机骨架。对其温度依赖性电导率的研究表明,Emim(+)(Emim(+) = 1-乙基-3-甲基溴化咪唑)在通道中的有序和无序对其电导率有贡献。