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在金属-有机骨架的通道中受限的 Emim+(Emim+ = 1-乙基-3-甲基咪唑鎓)的温度依赖性电导率。

Temperature-dependent conductivity of Emim+ (Emim+ = 1-ethyl-3-methyl imidazolium) confined in channels of a metal-organic framework.

机构信息

State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

Chem Commun (Camb). 2011 Nov 21;47(43):11933-5. doi: 10.1039/c1cc14702a. Epub 2011 Oct 5.

DOI:10.1039/c1cc14702a
PMID:21975950
Abstract

A 3D metal-organic framework, featuring three kinds of cation channels, was obtained through an ionothermal reaction. Investigation on its temperature-dependent conductivity indicates the contribution of order and disorder of the Emim(+) (Emim(+) = 1-ethyl-3-methyl imidazolium bromide) in the channel to its conductivity.

摘要

通过离子热反应得到了一种具有三种阳离子通道的三维金属有机骨架。对其温度依赖性电导率的研究表明,Emim(+)(Emim(+) = 1-乙基-3-甲基溴化咪唑)在通道中的有序和无序对其电导率有贡献。

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